4.7 Article

A highly conductive, transparent molecular charge-transfer salt with reversible lithiation

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 50, Pages 7179-7182

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03271a

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Funding

  1. U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [DE-SC0018631]
  2. U.S. Army Research Office [W911NF-18-2-0202]
  3. NSAF [U1530402]

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Here, we describe the high conductivity in a molecular charge-transfer hydrocarbon both as a bulk solid and films. In particular, the high electrical conductivity (similar to 30 S cm(-1)) and transparency (similar to 80%) of the TTF-TCNQ thin film allowed us to develop its application in all-organic freestanding photodetectors. More importantly, the fabricated TTF-TCNQ thin film can be used as a lithium-ion battery electrode with a specific capacity of similar to 250 mA h g(-1).

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