4.7 Article

Efficient modulation of photoluminescence by hydrogen bonding interactions between inorganic [MnBr4]2- anions and organic cations

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 51, Pages 7303-7306

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03038g

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Funding

  1. National Natural Science Foundation of China [21671187, 21871048]

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The different hydrogen bond interactions in two organic-inorganic hybrid manganese halide compounds, namely [A](2)[MnBr4] (A = N-butyl-N-methylpyrrolidinium ([P14](+)) for (1) and N-butyl-N-methylpiperidinium ([PP14](+)) for (2)), lead to distinct photoluminescence quantum yields (81% for 1; 55% for 2). Further applications of luminescent 1 are also developed.

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