Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 6, Issue 13, Pages 2210-2214Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9qo00471h
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Funding
- Singapore National Research Foundation, Prime Minister's Office [R-143-000-A15-281]
- National University of Singapore [R-143-000-695-114]
- National Natural Science Foundation of China [21672158]
- KFUPM-NUS Collaborative Fund [NUS15103, R-143-004-617-597]
- China Scholarship Council (CSC)
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A [3 + 2] annulation between the Morita-Baylis-Hillman (MBH) carbonates and pyrazoloneyldiene oxindoles catalyzed by (S)-SITCP has been developed. Structurally novel bispiro[pyrazolone-3,3 '-oxindoles] containing two contiguous quaternary stereogenic centers were created in excellent yields, in a diastereospecific and highly enantioselective manner.
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