Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 7, Issue 23, Pages 14070-14078Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta03272j
Keywords
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Funding
- National Natural Science Foundation of China (NSFC) [21702154, 51773157]
- Natural Science Foundation of Hubei Province [2017CFB118]
- Fundamental Research Funds for the Central Universities [2042017kf0269]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB12010200]
- National Natural Science Foundation of China [21572234, 21661132006]
- NSFC [51871169, 51671148, 51601132]
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Realizing the triple functions of simultaneously improved open circuit voltage (V-oc), short circuit current density (J(sc)) and fill factor (FF) enabled by material design is a vital challenge for achieving efficient and stable polymer solar cells (PSCs). Herein, we developed a new wide-bandgap donor-acceptor (D-A) copolymer, J101, with a down-shifted highest occupied molecular orbital (HOMO) level by chlorine substitution on its 2-alkyl-benzo[d][1,2,3]triazole (BTz) unit. The PSCs fabricated by combining the J101 donor with the indenoindene-containing fused-ring electron acceptor ZITI demonstrated a remarkable power conversion efficiency (PCE) of 14.43% with a high V-oc of 0.937 V, a high J(sc) of 21.25 mA cm(-2) and a high FF of 72.48%, benefitting from the low HOMO level of the donor, suitable nanoscale morphology, efficient charge transport properties and reduced recombination losses. Furthermore, semitransparent PSCs based on the optimized J101:ZITI blend exhibited the best PCE of 11.04% with an average visible transmittance (AVT) of 21.69%. This work demonstrates that the chlorine substituted BTz unit is an excellent electron-accepting building block for high-performance opaque and semitransparent PSCs.
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