4.7 Article

Successive carbene insertion into 9-phenyl-9-borafluorene

Journal

DALTON TRANSACTIONS
Volume 48, Issue 19, Pages 6319-6322

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt01032g

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Funding

  1. Welch Foundation [AA-1846]
  2. National Science Foundation [1753025]
  3. Division Of Chemistry
  4. Direct For Mathematical & Physical Scien [1753025] Funding Source: National Science Foundation

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The reactions of 9-phenyl-9-borafluorene with trimethylsilyldiazomethane in a 1:1 and 1:2 stoichiometry furnished the corresponding BC5 and BC6 heterocycles via the formal insertion of one and two carbene units.

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