Journal
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
Volume 80, Issue -, Pages 503-510Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jtice.2017.08.014
Keywords
MnO2; Supercapacitor; Nanocomposite electrodes; Solid-state supercapacitors
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Funding
- National Research Foundation of Korea [NRF-2015M3A7B 4050 424]
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Herein we developed a nanocomposite of MnO2 and multiwall carbon nanotubes (MWCNTs) deposited on a stainless-steel mesh substrate using a simple and scalable chemical approach to greatly expand the capacitive performance of MnO2-based electrodes. Electrochemical investigations of the chemically prepared MWCNTs/MnO2 nanocomposite showed that it has high specific capacitance (614 Fig), high specific energy (85.3 Wh/kg), and high stability over 2500 cycles. The enhanced capacitive performance of the MWCNTs/MnO2 nanocomposite was analyzed by calculating the surface-controlled and diffusion controlled charge components. A symmetric solid-state supercapacitor using a MWCNTs/MnO2 nanocomposite electrode and polyvinyl alcohol (PVA)-Na2SO4 gel electrolyte achieved a cell voltage of 1.0 V and a maximum specific capacitance of 204 F/g with an energy density of 28.33 Wh/kg. Furthermore, the assembled symmetric solid-state supercapacitor achieved coulombic efficiency of 99.04%. The excellent electrochemical features of the MWCNTs/MnO2 nanocomposite electrode make it a promising material for application in future capacitor-based energy storage systems. (C) 2017 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
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