Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 54, Pages 7812-7815Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02725d
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Funding
- National Natural Science Foundation of China [61805034]
- Scientific Research Foundation of UESTC for Postdoctoral Researchers [Y02006023647352, Y02006023601863]
- Fundamental Research Funds for the Central Universities
- Jiangsu Key Laboratory for Carbon Based Functional Materials & Devices, Soochow University
- Research Foundation of SCU for Postdoctoral Researchers [2018SCU12004]
- Scientific Research Foundation of UESTC for Young Teacher [ZYGX2016KYQD134]
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Nitrogen analogues of Chichibabin's and Muller's hydrocarbons, DPh-D and TPh-D, based on 1,2,4-benzotriazinyl (Blatter) were studied. The two diradicaloids with good chemical and thermal stability exhibit smaller singlet-triplet energy gaps (Delta ES-T from -1.05 to -1.27 kcal mol(-1)) than the hydrocarbon diradicaloids with the same bridges.
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