Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 55, Pages 7966-7969Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03099a
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Funding
- National Natural Science Foundation of China [21425207, 21801245]
- Beijing Natural Science Foundation [2192063]
- Chinese Academy of Sciences
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The N-heterocyclic carbene-catalyzed beta-addition of enals to 3-alkylenyloxindoles was developed. All of the beta-aryl, beta-alkenyl and beta-alkyl enals worked well for the reaction to give the corresponding 3,3-disubstituted oxindoles bearing contiguous all-carbon quaternary and tertiary stereocenters in good yields with moderate to high diastereoselectivities and excellent enantioselectivities.
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