4.8 Review

Reactions of organoboron compounds enabled by catalyst-promoted metalate shifts

Journal

CHEMICAL SOCIETY REVIEWS
Volume 48, Issue 13, Pages 3464-3474

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cs00180h

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Funding

  1. NIH [NIGMS R35GM127140]

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This tutorial review describes recent developments in catalytic reaction design that involve catalyst-promoted 1,2-metalate shifts as a critical part of the reaction mechanism. Issues pertaining to catalysis, stereoselectivity, and reaction mechanism are discussed.

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