4.7 Article

TiN modified SiC with enhanced strength and electrical properties

Journal

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 37, Issue 4, Pages 1373-1378

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2016.11.007

Keywords

Silicon carbide; Titanium nitride; Conductive ceramics; Ceramic composites; High strength SiC

Funding

  1. Department of the Army [W911W6-06-D-0013]

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SiC based composites were manufactured with varying TiN content (0-50 V%) using Al2O3 and Y2O3 sintering aids. Basic dilatometry measurements were performed to determine when densification begins within the composite system. Samples were consolidated via uni-axial hot pressing at 1900 degrees C to produce ceramic composites with >98% theoretical density. Electrical measurements show increasing TiN additions reduce resistivity and begin to plateau at 40-50V%. Resistivity decreased from 2.0 x 10(5) Omega-cm (0% TiN) to 2.0 x 10(-4) Omega-cm (50V% TiN). Flexural strengths were characterized and compared against a baseline (0% TiN) SiC. Strengths increased gradually with TiN content. A maximum strength 921 MPa was observed at 40V% TiN content vs. 616 MPa for the baseline SiC. This was a gain of 50% over baseline. Additions beyond that range did not produce further gains in strength. (C) 2016 Elsevier Ltd. All rights reserved.

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