Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 164, Issue 1, Pages A6366-A6372Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0471701jes
Keywords
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Funding
- Vehicle Technologies Program, Hybrid and Electric Systems
- DOE Office of Vehicle Technologies [DE-AC02-06CH11357]
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In this work, various electrolyte additives designed for enhanced performance at high voltages were evaluated with elevated temperature potentiostatic holds with LiNi0.5Co0.2Mn0.3/Li4Ti5O12 full cells to determine their effect on the high voltage stability. Of the additives investigated, many showed increased oxidation current through the 60 hour potentiostatic holds test, and adversely affected both the capacity retention and interfacial impedance. Improved high voltage performance was observed with two additives, vinylene carbonate (VC) and 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (TTE), which was attributed to two different mechanisms of improvement. This work investigates some conclusions in the available literature of an additive molecule that decomposes on the charged cathode surface and passivates the surface against electrolyte oxidation. (C) The Author(s) 2017. Published by ECS. All rights reserved.
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