Journal
INDONESIAN JOURNAL OF CHEMISTRY
Volume 19, Issue 3, Pages 638-649Publisher
GADJAH MADA UNIV, DEPT CHEMISTRY
DOI: 10.22146/ijc.35681
Keywords
Ni(II); cloud point extraction; non-ionic surfactant; urine sample; UV-Vis spectrophotometer; FAAS
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The cloud point technique was effectively utilized for extraction and pre-concentration of nickel(II) in urine samples before measurement by UV-Vis spectrophotometer and AAS techniques. The metal response to a para-aminophenol (PAP) reagent in a non-ionic surfactant Triton X-114 medium was to form the Ni-PAP complex. The adopted concentration for PAP, concentration of Triton X-114, pH effect and water bath temperature, incubation time, salt effect, and interference effects were all optimized. The calibration curve was linear over the range of (0.0625-1.25) mg. L-1 with a correlation coefficient r(2) of 0.9682 for the UV-Vis spectrophotometer at a lambda(max) of 629 nm. The limit of detection was 0.005 mg/L. The relative standard deviation for six replicates was 1.07%. This method was applied successfully to determine copper (II) concentrations in 44 urine samples of occupational worker samples as determined by UV-Vis spectrophotometry and FAAS techniques.
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