Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 58, Pages 8458-8461Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03771c
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Funding
- University of Idaho
- NSF [DMR1157490]
- State of Florida
- National Science Foundation (NSF) [CHE-1855681]
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The first transition metal mediated reductive coupling of diazoesters through the terminal nitrogens is reported. The resulting tetrazene-bridged bis(diazenylacetate) serves as a novel dinucleating ligand to iron(III). DFT calculations suggest that the reductive coupling takes place via a kappa(2) intermediate, which induces significant radical character on the terminal nitrogen.
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