4.8 Article

Organic aluminum hydrides catalyze nitrile hydroboration

Journal

GREEN CHEMISTRY
Volume 21, Issue 14, Pages 3812-3815

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc01659g

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Funding

  1. National Nature Science Foundation of China [21671018, 21872005]

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Economical and eco-friendly aluminum hydrides were shown to be highly efficient catalysts for the solvent-free hydroboration of various nitriles using pinacolborane. The catalytic activities of three organic aluminum hydrides were compared. Mechanism investigation experiments revealed that nitrile was reduced to an imine intermediate by aluminum hydrides.

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