Journal
DALTON TRANSACTIONS
Volume 48, Issue 27, Pages 9935-9938Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt01947b
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Funding
- Australian Synchrotron
- WSU Master of Research scholarship program
- AINSE Honours Scholarship program
- Australian Research Council [FT140100273]
- Australian Postgraduate Award (APA)
- WSU Top-up Award
- Australian Research Council [FT140100273] Funding Source: Australian Research Council
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The self-assembly of a mixed-spin [Fe4L6](8+) tetrahedral cage is reported. The cage undergoes temperature induced spin-crossover with a 29 K hystereisis. Variable temperature X-ray photoelectron spectroscopy (VT-XPS), combined with SQUID data, allowed differentiation between the surface and bulk magnetic properties.
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