4.7 Article

A self-assembled perylene diimide nanobelt for efficient visible-light-driven photocatalytic H2 evolution

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 56, Pages 8090-8093

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03465j

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Funding

  1. National Natural Science Foundation of China [21421004, 21772040, 21572062]
  2. Fundamental Research Funds for the Central Universities [222201717003]
  3. Programme of Introducing Talents of Discipline to Universities [B16017]

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In this communication, a self-assembled supramolecular system consisting of phosphoric acid substituted perylene diimide (P-PMPDI) has been successfully developed for highly efficient photocatalytic hydrogen evolution. Compared with a carboxylic substituent perylene diimide (P-CMPDI), P-PMPDI showed a superior H-2 evolution reaction rate of 11.7 mmol g(-1) h(-1) and a recorded apparent quantum yield (AQY) of 2.96% at 550 nm.

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