Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 59, Pages 8528-8531Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02744k
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Funding
- JSPS KAKENHI [JP17H03043, JP18H02032]
- Japan Science and Technology Agency (JST) [JPMJSC1601]
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We describe the preparation of the crystalline and glassy state of a coordination polymer displaying proton conduction and guest-accessible porosity. EXAFS and solid-state NMR analyses indicated that pyrophosphate and phosphate ions are the main proton transporters in the glass and that homogeneously distributed 5-chloro-1H-benzimidazole in the glass provides the porosity.
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