4.7 Article

[2+2] Halogen-bonded boxes employing azobenzenes

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 60, Pages 8768-8771

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03061a

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Funding

  1. Fonds der Chemischen Industrie via a Kekule Fellowship
  2. Strategic Research Fund of Heinrich Heine University [F-2018/1460-4]

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Herein, we report the synthesis and crystal structures of three [2+2] supramolecular boxes assembled by halogen bonding. The discrete, two-dimensional boxes with a length of 25-30 A are based on rigid u-shaped halogen acceptors paired with highly fluorinated, azobenzenes bearing halogen bond donors.

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