Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 60, Pages 8776-8779Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02849h
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Funding
- Volkswagenstiftung
- DFG [HE 7036/5]
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A chiral photoswitchable nanoporous material with remote-controllable enantioselective adsorption capacity is presented. This metal-organic framework possesses both homochiral d-camphoric acid and light-responsive azobenzene moieties. Although the structure at the chiral moieties is unaffected, the trans-cis-azobenzene-photoisomerization changes the pore environment and, thus, switches the enantioselective adsorption behavior of the homochiral MOF.
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