4.7 Article

A radical capture mechanism for immediate Csp2-H bond hydroxylation via a heterogeneous Cu-graphene catalyst

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 61, Pages 8915-8918

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02906k

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Funding

  1. Natural Science Foundation of Shandong Province [GG201809180289]

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A radical capture mechanism via a synergistic heterogeneous Cu2O-rGO catalyst for Csp(2)-H bond immediate hydroxylation has been developed. This protocol suggests the involvement of a C-centered radical (C-center dot), generated through an O-centered radical ((OH)-O-center dot) initiated hydrogen atom transfer (HAT) process.

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