Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 22, Pages 7440-7443Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b03127
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Funding
- Alexander von Humboldt Foundation
- Deutsche Forschungsgemeinschaft
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Herein, we report a conceptually novel borylation reaction proceeding via a mild photoinduced decarboxylation of redox-activated aromatic carboxylic acids. This work constitutes the first application of cheap, and easily prepared N-hydroxyphthalimide esters as aryl radical precursors and does not require the use of expensive transition metals or ligands. The reaction operationally simple, scalable, and displays broad scope and functional group tolerance.
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