Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 27, Pages 9120-9123Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b04363
Keywords
-
Categories
Funding
- Deutsche Forschungsgemeinschaft [ME 1805/13-1]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1565669] Funding Source: National Science Foundation
Ask authors/readers for more resources
A reaction design is reported in which a substrate-bound chiral Lewis acid complex absorbs visible light and generates an excited state that directly reacts with, a cosubstrate in a highly stereocontrolled fashion. Specifically, a chiral rhodium complex catalyzes visible, light-activated intermolecular [2+2] cycloadditions, providing a wide range of cyclobutanes with up to >99% ee and up to >20:1 d.r. Noteworthy is the ability to create vicinal all-carbon-quaternary stereocenters including spiro centers in an intermolecular fashion.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available