Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 8, Pages 2904-2907Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b13299
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Funding
- National Basic Research Program of China [973-2015CB856600]
- National Nature Science Foundation of China [21225210, 21421091, 21532009, 21472219]
- Chinese Academy of Sciences [XDB20000000]
- CAS Interdisciplinary Innovation Team
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A novel asymmetric radical trifluoromethylarylation of alkenes has been developed, which provides an efficient approach to access chiral CF3-containing 1,1-diarylmethane derivatives with good to excellent enantio-selectivity. Various vinyl arenes and aryl boronic acids are compatible with these conditions. The utility of the method is demonstrated by accessing modified bioactive molecules.
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