Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 44, Pages 15580-15583Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b08575
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Funding
- NSF [CHE-1665125]
- University of North Carolina
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Catalytic enantioselective addition of N-heteroarenes to terminal and internal 1,3-dienes is reported. Reactions are promoted by 5 mol % of Rh catalyst supported by a new chiral pincer carbodicarbene ligand that delivers allylic substituted arenes in up to 95% yield and up to 98:2 er. Mechanistic and X-ray evidence is presented that supports that the reaction proceeds via a Rh(III)-eta(3-)allyl.
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