Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 23, Pages 7709-7712Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b03781
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Funding
- National Basic Research Program of China [973-2015CB856600]
- National Nature Science Foundation of China [21532009, 21421091, 21472219]
- Program of Shanghai Academic/Technology Research Leader [17XD1404500]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- CAS Interdisciplinary Innovation Team
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A novel copper-catalyzed arylation of benzylic C-H bonds with nucleophilic arylboronic acids has been developed that provides an efficient way to synthesize various 1,1-diarylalkanes with a broad substrate scope and excellent functional group compatibility. The reactions occur at room temperature using alkylarenes as the limiting reagents, which allows access to the arylation of the more valuable and complex bioactive compounds.
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