Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 6, Pages 2212-2215Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b00651
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Funding
- National Science Foundation [DMR1149067]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [W-31-109-Eng-38]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1149067] Funding Source: National Science Foundation
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Metal coordination and peptide-directed self-assembly are two proven methods for creating defined supramolecular architectures. Here, we report a new class of crystalline materials based on coiled-coil peptides bearing unnatural metal-chelating terpyridine moieties. High-resolution structural characterization of lattices formed in the presence of Cu2+ reveals a general assembly mechanism. Subtle sequence variation in the modular synthetic ligand dictates assembly morphology.
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