Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 8, Pages 3153-3160Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b12663
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- NIH [GM-118641]
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Catalytic enantioselective conjunctive cross couplings that employ Grignard reagents are shown to furnish an array of nonracemic chiral organoboronic esters in an efficient and highly selective fashion. The utility of sodium triflate in facilitating this reaction is two-fold: it enables ate complex formation and overcomes catalytic inhibition by halide ions.
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