Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 27, Pages 9140-9143Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b04993
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Funding
- NSF CAREER program [CHE-1253385]
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A family of easily accessible light-activated hydrazone switches has been developed having thermal half-lives of up to 2700 years! Structure property analysis shows that replacing the rotor pyridyl group of our typical hydrazone switch with a phenyl one leads to the long-lived negative photochromic compounds. The switching properties of the hydrazones in both toluene and DMSO were assessed offering insights into the kinetics and thermodynamics of the switching process.
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