Journal
CHEMICAL SCIENCE
Volume 10, Issue 27, Pages 6666-6671Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9sc02035g
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Funding
- JSPS KAKENHI [15H03811]
- MEXT, Japan [18H04259]
- Toray Science Foundation
- Hoansha Foundation
- Program for Leading Graduate Schools: Interactive Materials Science Cadet Program
- Grants-in-Aid for Scientific Research [15H03811, 18H04259] Funding Source: KAKEN
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Nickel-catalyzed decarbonylation of N-acylated N-heteroarenes is developed. This method can be used to produce a variety of N-aryl heteroarenes, including pyrroles, indoles, carbazoles and phenoxazines, using benzoic acid derivatives as arylating reagents. Arylnickelamide intermediates that are relevant to the catalytic reaction were characterized by X-ray crystallography. When N-acylated benzimidazoles are used as substrates, decarbonylation accompanied 1,2-migration to form 2-arylated benzimidazoles.
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