Journal
CHEMICAL SCIENCE
Volume 10, Issue 27, Pages 6715-6720Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9sc00960d
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Funding
- JSPS [19K05485]
- Grants-in-Aid for Scientific Research [19K05485] Funding Source: KAKEN
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Silicon-tethered tetraynes possessing a 1,3-diyne moiety underwent consecutive hexadehydro- and tetradehydro-Diels-Alder reactions to give a series of fused polycyclic aromatic compounds containing a dibenzosilole skeleton. The benzene ring in the product acted as a 1,3-diene and reacted with the active alkyne as well as oxygen to provide [4 + 2] cycloadducts.
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