Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 31, Pages 10621-10624Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b05549
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Funding
- NSF [CHE1566007]
- NIH [GM074785]
- Harry and Cleio Greer Fellowship
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1566007] Funding Source: National Science Foundation
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One-electron reduction of [Fe(NO)(N3PyS)]BF4 (1) leads to the production of the metastable nonheme {FeNO}(8) complex, [Fe(NO)(N3PyS)] (3). Complex 3 is a rare example of a high-spin (S = 1) {FeNO}(8) and is the first example, to our knowledge, of a mononuclear nonheme {FeNO}(8) species that generates N2O. A second, novel route to 3 involves addition of Piloty's acid, an HNO donor, to an Fe-II precursor. This work provides possible new insights regarding the mechanism of nitric oxide reductases.
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