4.7 Article

The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

Journal

DALTON TRANSACTIONS
Volume 48, Issue 25, Pages 9053-9056

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt01322a

Keywords

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Funding

  1. JSPS KAKENHI from MEXT (Japan) [JP15H03777, JP15K13640]
  2. Nagoya City University
  3. Institute for Chemical Research at Kyoto University [2018-22]
  4. Daiko Foundation
  5. JURC (Kyoto University)
  6. IRCCS (Kyoto University)
  7. KURCA (Kyoto University)
  8. [JP16J05501]

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A stable 1,4-disilabenzene was generated from the reaction of a stable disilyne with 3-hexyne. Its photochemical isomerization afforded the corresponding disilabenzvalene, which was structurally characterized by a single-crystal X-ray diffraction analysis.

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