Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 33, Pages 11333-11336Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b06410
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Funding
- National Natural Science Foundation of China [21374016]
- Jiangsu Provincial Natural Science Foundation of China [BK20170024]
- Open Research Fund of State Key Laboratory of Bioelectronics, Southeast University
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In this Communication, we develop a two-step acyclic diene metathesis in situ polymerization/crosslinking method to synthesize uniaxially aligned main-chain liquid crystal elastomers with chemically bonded near infrared absorbing four-alkenyl-tailed croconaine-core cross-linkers: Because of the extraordinary photothermal conversion property, such a soft actuator material can raise its local temperature from 18 to 260 degrees C in 8 s, and lift up burdens 5600 times heavier than its own weight, under 808 nm near-infrared irradiation.
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