Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 31, Pages 10633-10636Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b05634
Keywords
-
Categories
Funding
- European Research Council (ERC) under the European Union' Horizon H2020 research program [716314]
- CNRS
- Ecole Polytechnique
- French National Agency [ANR-15-CE29-0019]
- GENCI-CINES/IDRIS [2016-x2016086830]
- European Research Council (ERC) [716314] Funding Source: European Research Council (ERC)
Ask authors/readers for more resources
The unique combination of a divalent organolanthanide fragment, Cp-2*Yb, with bipyrimidine (bipym) and a palladium bis-alkyl fragment, PdMe2, allows the rapid formation and stabilization of a Pd-IV tris-alkyl moiety after oxidative addition with MeI. The crucial role of the organolanthanide fragment is demonstrated by the substitution of bipym by the 4,5,9,10-tetraazaphenanthrene ligand, which drastically modifies the electronic structure and tunes the stability of the Pd-IV species.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available