Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 19, Pages 6538-6541Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b01956
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Funding
- Japan Society for the Promotion of Science (JSPS) [24655044, 24245011]
- JSPS KAKENHI [25107508, JP15H00861]
- Asahi Glass Foundation
- Mitsubishi Foundation
- JSPS [15J04635]
- Grants-in-Aid for Scientific Research [17H05352, 15H00915, 17H03027, 15J04635, 25107508, 15H00861, 17K14456, 16K05739] Funding Source: KAKEN
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A Ni(II) complex bearing an S2N2-type tetradentate ligand inspired by the active site of carbon monoxide dehydrogenase was found to selectively catalyze CO2 reduction to produce CO in a photocatalytic system using [Ru(bpy)(3)](2+) (bpy = 2,2'-bipyridine) as a photo sensitizer and 1,3-dimethy1-2-pheny1-2,3-dihydro-1H-benzo[d]imidazole (BIH) as an electron donor. The Ni(II) complex shows a high turnover number over 700 with high CO selectivity of >99% and quantum yield of 1.42% in the photocatalytic system.
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