Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 23, Pages 7753-7756Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b04640
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Funding
- DOE [DE-SC0009376]
- Basque Government
- Alexander von Humboldt foundation
- Keck Foundation
- U.S. Department of Energy (DOE) [DE-SC0009376] Funding Source: U.S. Department of Energy (DOE)
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A straightforward strategy allows for the synthesis of storable bicyclic (alkyl)(amino)carbenes (BICAACs), which feature enhanced sigma-donating and pi-accepting properties compared to monocyclic (alkyl)(amino)carbenes (CAACs). Due to the bicyclo [2.2.2]-octane skeleton, the steric environment around the carbene center is different from that of CAACs and similar to that observed in classical N-heterocyclic carbenes. The different electronic properties of BICAACs as compared to CAACs allow for ligand exchange reactions not only at a metal center, but also at main group elements.
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