Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 4, Pages 1195-1198Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b10578
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Funding
- Japan Society for the Promotion of Science (JSPS) [JP17H05164, JP26288095, JP17K19164]
- Accelerated Innovation Research Initiative Turning Top Science and Ideas into High-Impact Values (ACCEL) program from the Japan Science and Technology Agency (JST)
- Iketani Science and Technology Foundation
- Mitsubishi Foundation
- Sumitomo Foundation
- FY Individual Special Research Fund from KG University
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One-shot double, triple, and quadruple borylation reactions of triarylamines were developed through a judicious choice of boron source and Bronsted base. With the aid of borylation reactions, a variety of BN-doped nanographenes were synthesized in two steps from commercially available starting materials. An organic light emitting diode device employing BN-doped nanographene as an emitter exhibited deep pure-blue emission at 460 nm, with CIE coordinates of (0.13, 0.11), and an external quantum efficiency of 18.3%.
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