Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 5, Pages 1786-1789Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b12907
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Funding
- National Natural Science Foundation of China [21402096, 21421062]
- Tianjin Applied Basic Research Project and Cutting-edge Technology Research Plan [14JCYBJC41400]
- 1000-Youth Talents Plan
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Pd-catalyzed highly para-selective arylations of monosubstituted simple arenes with arylboronic acids to widely existed biaryls have been developed. Inspired by requisite amide-directing groups in reported selective oxidative couplings, amide ligands, especially DMF, are designed and found to be critical for the selectivity control in current arylations.
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