Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 21, Pages 7184-7187Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b03749
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- Max-Planck-Institut fur Kohlenforschung
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We report the first highly stereo- and regioselective hydrocyanation of terminal alkynes to furnish E-configured alkenyl nitriles. Acrylonitriles can be accessed on gram scale with broad substrate scope and functional group tolerance. The hydrocyanation reaction employs acetone cyanohydrin as a practical alternative to HCN gas.
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