Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 29, Pages 9847-9850Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b06288
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Funding
- NIGMS [R01 GM113878]
- NIH [S10 OD011980]
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The construction of quaternary centers is a common challenge in the synthesis of complex materials and natural products. Current cross-coupling strategies that can be generalized for setting these centers are sparse and, when known, are typically predicated on the use of reactive organometallic reagents. To address this shortcoming a new, photoredox-Ni dual catalytic strategy for the cross-coupling of tertiary organoboron reagents with aryl halides is reported. In addition to details on the cross coupling scope and limitations, full screening efforts and mechanistic experiments are communicated.
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