Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 34, Pages 11686-11689Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b05901
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- Purdue University
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1625543] Funding Source: National Science Foundation
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Methylenecyclopropanes are important synthetic intermediates that possess strain energies exceeding those of saturated cyclopropanes by >10 kcal/mol. This report describes a catalytic reductive methylenecyclopropanation reaction of simple olefins, utilizing 1,1-dichloroalkenes as vinylidene precursors. The reaction is promoted by a dinuclear Ni catalyst, which is proposed to access Ni-2(vinylidenoid) intermediates via C-Cl oxidative addition.
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