Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 31, Pages 10601-10604Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b04872
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- U.S. Department of Energy (DOE), Energy Efficiency and Renewable Energy's Geothermal Technologies Office (GTO)
- U.S. Department of Energy (DOE) [DE-AC05-76RL01830]
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Metal-organic frameworks (MOFs) have shown promising behavior for adsorption cooling applications. Using organic ligands with 1, 2, and 3 phenylene rings, we construct moisture-stable Ni-MOF-74 members with adjustable pore apertures, which exhibit excellent sorption capabilities toward water and fluorocarbon R134a. To our knowledge, this is the first report of adsorption isotherms of fluorocarbon R134a in MOFs. The adsorption patterns for these materials differ significantly and are attributed to variances in their hydrophobic/hydrophilic pore character associated with differences in pore size.
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