Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 17, Pages 6050-6053Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b01889
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Funding
- NSFC [21672195]
- Recruitment Program of Global Experts
- China Postdoctoral Science Foundation [2016M602014]
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A synthetic method to construct boron-handled cyclic molecules was developed based on a radical borylation/cyclization cascade of 1,6-enynes. The process was initiated by the chemo- and regio-controlled addition of an N-heterocyclic carbene-boryl radical to an alkene or alkyne, followed by ring closure to afford boron-substituted cyclic skeletons. Further molecular transformations of the cyclic products to synthetically useful building blocks were also demonstrated.
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