Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 38, Pages 13280-13283Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b07856
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- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Research and Development Corporation of Newfoundland and Labrador (RDC)
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Dithienylethene-containing molecules have been examined due to their photoswitching capabilities. We have prepared a bistable, optically triggered, metal-organic framework (MOP) containing a dithienylethene moiety that was synthesized and characterized. The advantage of this material is that, unlike other dithienylethene-containing MOFs, the properties of the pore can be changed via an optical trigger without the potential risk of structural damage to the framework. We illustrate the application of this MOF to chemical separations. With this class of materials, optically triggered conductivity, chemical storage and release, and sensing are possible.
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