Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 7, Pages 2593-2596Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b00924
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Funding
- JSPS KAKENHI [JP24109012, 26288019]
- Research Grants Council of Hong Kong [HKUST16303614, C5023-14G]
- CREST from the JST [14529307]
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [26288019, 24109012] Funding Source: KAKEN
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Tetra(o-tolyl)diborane(4), 1, was synthesized and characterized experimentally as well as theoretically by density functional theory (DFT) calculations. Exposure of 1 to H-2 (1 bar) at room temperature afforded the corresponding di(o-tolyl)hydroborane through cleavage of the H-H and B-B bonds. DFT calculations suggested a diarylboryl anion character for the transition state.
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