Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 7, Issue 30, Pages 17842-17853Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta04785a
Keywords
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Funding
- National Natural Science Foundation of China [21722606, 21676138, 21576137, 21808105]
- Natural Science Foundation of Jiangsu Province [BK20180709]
- Six Talent Plan [2016XCL031]
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The empiricism that extrinsic or doped materials universally perform much better than their intrinsic counterparts has been verified to be feasible in the adsorptive CO2 capture. Thus, a variety of N-doped solid adsorbents are well-engineered to adsorb CO2. However, the true nature of the N-doped sites in the aggregation state and the underlying mechanism of CO2 adsorption therein are difficult to determine. In the present study, four well-defined azacyclo copolymers with peculiar textural characteristics, uniformly arrays and tunably effective N-doped sites were fabricated to experimentally determine the precise relation between adsorbed CO2 molecules and the N-doped sites incorporated into an adsorbent. With multifaceted quantum chemical computations, induction forces were proven to account for the improved CO2 adsorption on the N-doped sites instead of the conventionally assumed generalized acid-base interaction. The negative electrostatic potentials were demonstrated to be the real cause for improving the CO2 adsorption and a robust indicator for the effectiveness of the N-doped sites. Besides, a precise linear function is proposed to quantitatively describe this subject-object relationship for the first time.
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