Studies on dielectric relaxation in ceramic multiferroic Gd1-xYxMnO3

Dielectric study over a broadband was carried out from 10 to 70 K on ceramic Gd1-xYxMnO3 (x=0.2, 0.3 and 0.4). For all the compositions, a prominent sharp peak about similar to 18 K was observed in the temperature dependence of both epsilon(T) and epsilon(T) at all frequencies, indicating a long-range ferroelectric (FE) transition. Using Cole-Cole fit to the permittivity data, the relaxation time and the dielectric strength epsilon were estimated. Temperature variation of (T) in the Arrhenius representation is found to be nonlinear (non-Debyean relaxation), with increasing barrier-activation energy over successive temperature-windows. Interestingly, for all the compositions, we witness a jump in (T) about the ferroelectric transition temperature, concurred by a broad-maximum in epsilon(T),signifying the critical slow down of relaxations near long-range FE-correlations.