Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 17, Issue 30, Pages 7131-7134Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ob01340g
Keywords
-
Categories
Funding
- NSFC [21572020]
Ask authors/readers for more resources
A novel electrophilic thiocyanating reagent, N-thiocyanato-dibenzenesulfonimide, was prepared and exhibited enhanced electrophilicity with a wide scope of substrates. Thus, it reacted with activated aromatics such as phenols, indoles, anilines and anisoles without a catalyst giving the corresponding thicyanate derivatives in high yields, while TfOH for unactivated arenes and hetero aromatics and Zn(OTf)(2) for ketones was used as the catalyst, respectively. It is noteworthy that internal alkenes and styrenes were bifunctionalized giving 1,2-amino thiocyanates in high yields.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available