Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 63, Pages 9315-9318Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc04530a
Keywords
-
Categories
Funding
- China Scholarship Council [201506250062]
- Alexander von Humboldt Foundation
- Deutsche Forschungsgemeinschaft (DFG) [INST 40/467-1 FUGG]
Ask authors/readers for more resources
Reaction of the arsinoamide [(Mes(2)AsNPh){Li(OEt2)(2)}] with the low-valent group 14 compounds, [{PhC((BuN)-Bu-t)(2)}ECl] (E = Si, Ge) and GeCl2 center dot dioxane, resulted in two different reaction pathways: simple substitution or substitution accompanied by an insertion step. As a result, either insertion products with an As-SiN unit and an As-Ge bond, or substitution products, in which the intact arsinoamide binds to the group 14 elements via the N atom, were obtained.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available