Journal
RSC ADVANCES
Volume 9, Issue 42, Pages 24212-24217Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ra04768a
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Funding
- National Natural Science Foundation of China [21871128]
- Shenzhen Innovation of Science and Technology Commission [JCYJ20170817110526264, ZDSYS201802081843490]
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The enantioselective conjugate addition of 2-naphthols to ortho-hydroxyphenyl substituted para-quinone methides has been achieved with the aid of a chiral phosphoric acid. Importantly, the reaction took place with excellent chemo- and regioselectivities. In addition, the protocol features a low catalyst loading, mild reaction conditions, and enables the formation of unsymmetrical triarylmethanes in good to high yields with generally high enantioselectivities.
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